<i>N</i> ‐Heterocyclic Imine‐Stabilized Binuclear Tin(II) Cations: Synthesis, Reactivity, and Catalytic Application
نویسندگان
چکیده
The reaction of Cp*Sn[OTf] (Cp* = C 5 Me ; OTf O 3 SCF ) with one equivalent IPrNLi (IPrN bis(2,6-diisopropylphenyl)imidazolin-2-iminato) resulted in the binuclear [OTf]-bridged tin complex 1 . Similarly, [BF 4 ]-bridged bimetallic 2 was synthesized by Cp*Sn[BF ] (1 eq.). It also possible to prepare from via an anion exchange reaction. high-yield conversion into iodostannylene [IPrNSnI] accomplished treatment LiI. catalytic potential and demonstrated hydroboration carbonyls.
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2022
ISSN: ['0044-2313', '1521-3749']
DOI: https://doi.org/10.1002/zaac.202200220